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Sunday, 20 January 2019

Linoleic Acid Derivative DCP-LA Sheds Light on Treatment of Alzheimer’s Disease




Thenumber of Alzheimer’s Disease (AD) patients is considerably mounting in association with prolongation of life span and AD is currently a major burden on society. No beneficial anti-AD drug, however, has been provided as yet. The most urgent issue, therefore, is to develop drugs for AD.

Wehave found that cis-unsaturated free fatty acids such as arachidonic, linoleic and linolenic acid, persistently facilitates hippocampal synaptic transmission by targeting presynaptic nicotinic ACh receptor under the control of PKC. Cis-unsaturated free fatty acids, however, are promptly metabolized and decomposed before arriving in the brain, even though the fatty acids are orally or intravenously taken into the body. To resolve this problem, we have synthesized a variety of derivatives of cis-unsaturated free fatty acids, that exhibit stable bioactivities, and obtained the most effective compound a linoleic acid derivative with cyclopropane rings instead of cis-double bonds.

Beneficialanti-AD drugs require protection of neuronal apoptosis and facilitation of synaptic transmission relevant to cognitive functions. I show here that DCP-LA has the actions of both anti-apoptosis and cognitive enhancement. Tau, which is abundantly expressed in neurons of the central nervous system, stabilizes microtubules by interacting with tubulin. When phosphorylated excessively, Tau becomes a trigger for tauopathies. Tauopathies are a class of neurodegenerative diseases associated with aggregation of hyperphosphorylated Tau in an insoluble form in the brain, referred to as Neurofibrillary Tangles (NFT), which include AD, frontotemporal dementia and parkinsonism linked to chromosome 17, progressive supranuclear palsy, Pick’s disease, and corticobasal degeneration. AD is a really tragic disease in which a human being loses human dignity. AD is characterized by extensive deposition of amyloid β (A β) and formation of NFT. To date, none of Aβ-directed drugs for AD.

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